The Kα and Kβ emissions are actually closely spaced doublets, because transitions can occur between two possible electronic configurations, which differ slightly in energy. Usually, the two Kα wavelengths (Kα1 and Kα2) are used in crystallography. The Kβ emission and much of the white radiation can be removed by the use of an appropriate filter (Ni metal for Cu radiation; Zr for Mo radiation) or by the use of a monochromator. The wavelengths of the commonly used Cu and Mo targets are:

Target Kα1 Kα2 Kα
Cu 1.54056Å 1.54439Å 1.54184Å
Mo 0.70930Å 0.71359Å 0.71073Å

The wavelength in the last column is the intensity weighted average, which is generally the one used because Kα1 and Kα2 are not usually resolved.


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