The Kα and Kβ emissions are actually closely spaced doublets, because transitions can occur between two possible electronic configurations, which differ slightly in energy. Usually, the two Kα wavelengths (Kα1 and Kα2) are used in crystallography. The Kβ emission and much of the white radiation can be removed by the use of an appropriate filter (Ni metal for Cu radiation; Zr for Mo radiation) or by the use of a monochromator. The wavelengths of the commonly used Cu and Mo targets are:
Target | Kα1 | Kα2 | Kα |
---|---|---|---|
Cu | 1.54056Å | 1.54439Å | 1.54184Å |
Mo | 0.70930Å | 0.71359Å | 0.71073Å |