It is useful to develop a version of Bragg's Law in reciprocal space. In the diagram on the right,
a circle of radius 1/λ has been drawn on a reciprocal lattice. The origin of the lattice is at 0;
the crystal is at C; the X-ray beam is along the 0CB direction; lattice point P is on the circumference of
the circle; the angle 0BP is labeled as θ. The triangle 0-B-P-0 is inscribed in a circle
and therefore the angle 0PB is a right angle. The angle BCP is 180° - 2θ (the triangle B-C-P-B is
an isosceles triangle because two of the sides are equal to 1/λ). Thus, the angle 0CP is 2θ.
The length of OP is 1/dhkl (OP is the vector from the origin to reciprocal lattice point hkl); the
length of OB is 2/λ (OB is the diameter of the circle). Finally, sinθ = OP/OB and, thus,
sinθ = λ/2dhkl which is just Bragg's Law rearranged: 2dhkl sinθ = λ.
Using this construction, if a crystal is rotated about the origin of the reciprocal lattice, 0, whenever a lattice
point comes into contact with the “circle of reflection”, Bragg's Law is fulfilled and a reflection occurs.
The direction of the reflected beam is along CP (the angle between the direct beam and the reflected beam is
2θ).
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