If this expression is differentiated with respect to each x,
m simultaneous equations are obtained (for the m
adjustable parameters):
If Fc is expanded as a truncated Taylor series,
the following equation results:
in which ΔF is (Fobs - Fcalc). Rearranging and
collecting terms leads to
and, finally,
This is the jth of m normal equations that yield the parameter shifts needed to
improve the agreement of Fobs and Fcalc. In this expression, the j-index
refers to the parameter with which the the derivative is being taken; the i-index
refers to the Taylor expansion of Fc for reflection hkl.